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Even though creating an Amazon store isnt a burning desire, this tutorial will give you an opportunit to learn how to code a webservice. You will use SOAP to access the Amazon product database through Amazon Web Services (AWS).
VoiceXML is currently an application you should be learning to develop with.
Here is a good introduction of the Grid architecture and information about the Globus toolkit for building applications for information exchange on the Grid and help for developers who want to integrate Web Services and Grid computing.